Organic Chemistry
Halogen can be estimated by:
0.3780 gm of an organic chloro compound gave 0.5740 gm of silver chloride in Carius estimation. Calculate the percentage of chlorine present in the compound (in nearest integer).(If answer is X, then enter $$\dfrac X6$$)
Percentage of CI $$=\displaystyle \frac{35.5}{143.5}\times \frac{Weight \,of \, AgCl\times 100}{Weight\, of\, compound}$$
$$= \displaystyle \frac{35.5\times 0.574\times 100}{143.5\times 0.378}$$
$$= 37.57$$%
Hence, percentage of chlorine (in nearest integer) = $$38$$.
Halogen can be estimated by:
In Carius method halogens are estimated as:
0.301 g of an organic compound gave 0.282 g of AgBr by carius method. The % of Br is:
In Carius method, of estimation of halogens, $$250\ mg$$ of an organic compound gave $$141\ mg$$ of $$AgBr$$. The percentage of bromine in the compound is:(Atomic mass $$Ag = 108; Br = 80$$)
0.3780 g of an organic chloro compound gave 0.5740 g of silver chloride in Carius estimation. Calculate the percentage of chlorine present in the compound.
Quantitative estimation of $$C$$, $$H$$ and extra elements (e.g.$$ N$$,$$S$$, $$P$$ and halogens) is carried out by Liebig’s combustion, Carius, Dumas, and Kjeldahl’s method. Carius method is used for the quantitative estimation of:
Fill in the blanks : In Carius method for the estimation of halogens, the organic compound is heated with ................. and a few crystals of ............. in a sealed tube.
An organic compound which produces a bluish green coloured flame on heating in presence of copper is :
To determine the amount of halogen in an organic compound, the compound is heated with fuming $$ HNO_3$$ in presence of _________ .
Beilstein test is reliable test for halogens in organic compounds.