Solutions
In which case van't Hoff factor is maximum (assuming no hydrolysis)?
A $$1.2$$% of solution of $$NaCl$$ is isotonic with $$7.2$$% of solution of glucose. Calculate the van't Hoff's factor of $$NaCl$$ solution.
The molar masses of NaCl and glucose are 58.5 g/mol and 180 g/mol respectively.
The expression for the osmotic pressure is as follows:
$$\pi =iCRT$$
Since the two solutions are isotonic, they have equal osmotic pressure.
$$\pi (NaCl)=\pi (glucose)$$
$$i_{NaCl}\times \dfrac{1.2}{58.5}=1\times \dfrac{7.2}{180}$$
$$i_{NaCl}=1.95$$
In which case van't Hoff factor is maximum (assuming no hydrolysis)?
At same temperature which pair of the following solutions are isotonic?
The value of van't Hoff factors for $$KCl, NaCl$$ and $${K}_{2}{SO}_{4}$$, respectively, are :
If $$\alpha$$ is the degree of dissociation of $${Na}_{2}{SO}_{4}$$, the vant Hoff's factor ($$i$$) used for calculating the molecular mass is:
Which of the following salt has the same value of Van't Hoff factor i as that of $$K_3 [Fe(CN)_6]$$?
The Van't Hoff factor, i for a $$0.2$$ molal aqueous solutions of urea is:
The Van't Hoff factor for sodium phosphate would be:
The freezing point of a solution containing 5.85 g of $$NaCl$$ in 100g of water is $$-3.348^o$$C. Calculate van't Hoff factor 'i' for this solution. What will be the experimental molecular weight of NaCI? ($$K_f$$ for water = $$1.86 K kg mol^{-1}$$, at. wt. Na = 23, Cl = 35.5)