Current Electricity
The electrochemical equivalent of a material depends on
A current of $$16$$ ampere flows through molten $$NaCl$$ for $$10$$ minute. The amount of metallic sodium that appears at the negative electrode would be
Amount of $$Na^+$$ deposited
$$w=zIt$$
$$w=\dfrac{at \,wt.}{n\times f}\times I\times t$$ at wt. of $$Na=23$$
$$w=\dfrac{23}{1\times f}\times 16\times 10\times 60$$
$$w=\dfrac{220800}{f}\Rightarrow \dfrac{220800}{96500}$$
$$w=2.28gm$$ $$[w\approx 2.3gm]$$
The electrochemical equivalent of a material depends on
The amount of substance liberated on electrodes during electrolysis when 1 coulomb of electricity is passed, is
In $$CuSO_{4}$$ solution when electric current equal to $$2.5$$ Faraday is passed, the gm equivalent deposited on the cathode is
In an electroplating experiment, m gm of silver is deposited when 4 ampere of current flows for 2 minutes. The amount ( in gm ) of silver deposited by 6 ampere of current for 40 second will be
A steady current of 5 amps is maintained for 45 mins. During this time it deposits 4.572 gms of zinc at the cathode of a voltameter. E.C.E. of zinc is
The electrochemical equivalent of magnesium is $$0.126 mg / C$$. A current of $$5 A$$ is passed in a suitable solution for 1 hour. The mass of magnesium deposited will be
If nearly $$10^{5}$$ coulomb liberate 1 gm equivalent of aluminium, then the amount of aluminium ( equivalent weight 9 ) deposited through electrolysis in 20 minute by a current of $$50$$ amp will be
In a copper voltameter, mass deposited in 30 second is m gm. If the time-current graph is as shown in figure, ECE of copper is
The negative Zn pole of a Daniel cell, sending a constant current through a circuit, decreases in mass by 0.13g in 30 minute. If the electrochemical equivalent of Zn and Cu are 32.5 and 31.5 respectively, the increase in the mass of the positive Cu pole in this time is
In a copper voltameter, mass deposited in 6 minutes is m gram. If the current-time graph for the voltameter is as shown here, then the E.C.E of the copper is