Acids, Bases and Salts
In the titration of $$NaOH$$ and $$HCl$$, which of the following indicator will be used?
A solution containing $$Na_{2}CO_{3}$$ and $$NaOH$$ requires $$300\ mL$$ of $$0.1\ N\ HCl$$ using phenolphthalein as an indicator. Methyl orange is then added to the above-titrated solution when a further $$25\ mL$$ of $$0.2\ N\ HCl$$ is required. The amount of $$NaOH$$ present in the original solution is:
$$300\ mL\ HCl$$ of $$0.1\ N$$ neutralises entire amount of $$NaOH$$ and $$1/2$$ of $$Na_{2}CO_{3}$$. Remaining $$1/2$$ of $$Na_{2}CO_{3}$$ is neutralised by $$25\ mL$$ of $$0.2\ N\ HCl$$, i.e., $$50\ mL$$ of $$0.1\ N\ HCl$$.
Thus, $$250\ mL$$ of $$0.1\ N\ HCl$$ is required to neutralise $$NaOH$$ completely.
$$N_{1}V_{1}(NaOH) = N_{2}V_{2}(HCl)$$
$$= 0.1\times 250$$
$$= 25$$
$$W_{NaOH} = \dfrac {ENV}{1000} = \dfrac {40\times 25}{1000} = 1\ g$$.
In the titration of $$NaOH$$ and $$HCl$$, which of the following indicator will be used?
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0.1 N solution of $${ Na }_{ 2 }{ CO }_{ 3 }$$ is titrated with 0.1 N HCl, best indicator is :
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