Organic Compounds Containing Nitrogen
$$Complete \ the \ following:$$
An aromatic compound $$A$$ of molecular formula $${C}_{7}{H}_{7}ON$$ undergoes a series of reactions as shown. Write the structures of $$A,B,C,D$$ and $$E$$ in the following reactions:
1. $$A$$ undergoes Hoffman Bromamide reaction to form Aniline, hence $$A$$ has to be Benzamide.
2. Aniline undergoes Diazotisation process to form Benzene Diazonium Chloride ($$B$$)
3. ($$B $$) reacts with $$Et-OH$$, gets reduced to form Benzene($$C$$)
4. ($$B$$) also reacts with $$KI$$ to form Iodobenzene($$E$$)
5. Aniline undergoes Carbylamine reaction ($$CHCl_3 + KOH$$) to form
Phenyl Isocyanide ($$D$$).
$$Complete \ the \ following:$$