Subjective Type

Answer the following:
(a) The triple-point of water is a standard fixed point in modern thermometry. Why? What is wrong in taking the melting point of ice and the boiling point of water as standard fixed points (as was originally done in the Celsius scale )?
(b) There were two fixed points in the original Celsius scale as mentioned above which were assigned the number $$0^oC$$ and $$100^oC$$ respectively. On the absolute scale one of the fixed points is the triple-point of water, which on the kelvin absolute scale is assigned the number 273.16 K. What is the other fixed point on this (kelvin) scale?
(c) The absolute temperature (Kelvin scale ) T is relate to the temperature $$t_{c}$$ on the Celsius scale by $$t_{c}=T-273.15$$. Why do we have 273.15 in this relation and not 273.16?
(d) What is the temperature of the triple-point of water on an absolute scale whose unit interval size is equal to that of the Fahrenheit scale ?
Solution
(a) Triple-point has a unique temperature; fusion point and boiling point temperatures depend on pressure.
(b) The other fixed point is the absolute zero itself.
(c) Triple-point is $$0.01^oC $$, not $$0^oC$$.
(d) $$T=273.15 \times 9/5 = 491.69$$
The temperature and pressure at which a substance can exist in equilibrium in the liquid, solid, and gaseous states.It is unique and constant. The problem with Celsius scale is that boiling and melting point change with atmospheric pressure at that place.
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