Single Choice

Consider the following statements in respect of lanthanoids : (i) the basic strength of hydroxides of lanthanoids increases from $$ La(OH)_3\ to\ Lu(OH)_3 $$ (ii) The lanthanoid ions $$ Lu^{3+}, Yb^{2+} and \ Ce^{4+} $$ are diamagnetic . Which of the statement (s) given above is/are correct?

A(i) only
B(ii) only
Correct Answer
CBoth (i) and (ii)
DNeither (i) nor (ii)

Solution

Basic strength decreases from $$\mathrm{La(OH)_{3}}$$ to $$\mathrm{Lu(OH)_{3}}.$$

Configurations of
$$\mathrm{Ce = [Xe] 4f^{1} \,5d^{1} \,6s^{2}\ \ ; \, \implies Ce^{4+} = [Xe]}$$
$$\mathrm{Yb = [Xe] 4f^{14} \,6s^{2}\ \ \ \ \ \ \ \ ; \, \implies Yb^{2+} = [Xe]4f^{14}}$$
$$\mathrm{Lu = [Xe]4f^{14} \,5d^{1} \,6s^{2} \ ; \, \implies Lu^{3+} = [Xe]4f^{14}}$$

$$\implies$$ $$\mathrm{Ce^{4+}, \ Yb^{2+} \ \& \ Lu^{3+}}$$ are diamagnetic in nature.

So, only statement (i) is incorrect.
Hence, Option "B" is the correct answer.


SIMILAR QUESTIONS

d - block and f - block Elements

Which of the following Lanthanoid is radioactive?

d - block and f - block Elements

The only radioactive element among the lanthanoids is

d - block and f - block Elements

Which of the following lanthanide is commonly used?

d - block and f - block Elements

Knowing that the Chemistry of lanthanoids $$(\mathrm{L}\mathrm{n})$$ is dominated by its $$+3$$ oxidation state, which of the following statements is incorrect?

d - block and f - block Elements

In context of the lanthanoids, which of the following statements is not correct?

d - block and f - block Elements

Only lanthanide which is radioactive is:

d - block and f - block Elements

Choose the incorrect statement among the following:

d - block and f - block Elements

What is the general molecular formula of the products obtained on heating lanthanoids (Ln) with sulphur?

d - block and f - block Elements

Although $$+3$$ is the characteristic oxidization state for lanthanoids but cerium also shows $$+4$$ oxidation state because?

d - block and f - block Elements

Although $$+3$$ is the characteristic oxidization state for lanthanoids but cerium also shows $$+4$$ oxidation state because?

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