Subjective Type

Describe the following: Cross aldol condensation

Solution

$$\textbf {Cross aldol condensation:}$$ Condensation between 2 different aldehydes or ketones, at least one of which contains ∝ – hydrogen is called aldol condensation. It is a useful synthetic tool only when one of the aldehyde or ketone does not contain $$∝ –$$ hydrogen. This is because if both the aldehydes or ketones contain $$∝ –$$ hydrogen it gives a mixture of four different products.
eg:- Condensation between formaldehyde and acetaldehyde in the presence of dil $$NaOH$$ (aq)


SIMILAR QUESTIONS

Physical World

What is meant by the following terms ? Give an example of the reaction in each case. (i) Cyanohydrin (ii) Acetal (iii) Semicarbazone (iv) Aldol (v) Hemiacetal (vi) Oxime (vii) Ketal (vii) Imine (ix) 2,4-DNP-derivative (x) Schiffs base

Physical World

When propanal reacts with 2-methylpropanal in presence of $$NaOH$$, four different products are formed. The reaction is known as:

Physical World

Aldol condensation does not occur between:

Physical World

Reaction between benzaldehyde and acetophenone in presence of dilute $$NaOH$$ is known as:

Physical World

Aldol condensation between which of the following two compounds followed by dehydration gives methyl vinyl ketone?

Physical World

Which of the following gives condensation with hydroxyl amine but does not undergo self condensation?

Physical World

Complete the following: $$PhCOPh + KOH \longrightarrow (A) + (B)$$

Physical World

How will you bring about the following conversions in not more than two steps ? Benzaldehyde to 3-Phenylpropan-1-ol

Physical World

Complete each synthesis by giving the missing starting material, reagent, or products.

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