Polymers
The copolymer formed by addition polymerization of styrene and acrylonitrile in the presence of peroxide is:
(i) Arrange the following compounds in the ascending order of their basic strength and give reasons for your answer: Methylamine, Aniline, Ethylamine, Diethyl ether (ii) Name the monomers and the type of polymerization in each of the folloiwng polymers: (a) Polyester (b) Bakelite
(i) Increasing order of basic strength is as follows:
Diethylether < Aniline < methylamine < ethylamine
Reason : $$+I$$ effect of alkyl groups increases the basic strength of acids and aromatic amines are weaker bases than aliphatic amines due to delocalisation of lone pair of electrons (resonance).
(ii) (a) Monomer f Polyester: Ethylene glycol and Terephthalic acid
Type of polymerisation: Condensation Polymerisation
(b) Monomer of Bakelite: Phenol and Formaldehyde
Type of polymersation : Condensation polymerisation
The copolymer formed by addition polymerization of styrene and acrylonitrile in the presence of peroxide is:
Which of the following polymers is not correctly matched?
cis-Polyisoprene possesses elastic property because:
Which of the following is an addition polymer?
Describe how Thiokol is synthesised?
(MCPB meta -chloro perbenzoic acid) stereochemistry of the product of the above reaction is :
Name the type of polymerisation (addition or condensation) and name the monomers in polyethylene.