Single Choice

In acidic medium, $$H_2O_2$$ changes $$Cr_2O_7^{- 2}$$ to $$CrO_5$$ which has two ($$-O- O-$$) bonds oxidation state of $$Cr$$ in $$CrO_5$$ is:

A5
B3
C6
Correct Answer
D-10

Solution

In acidic medium, $$H_2O_2$$ changes $$Cr_2O_7^{- 2}$$ to $$CrO_5$$ which has two ($$-O- O-$$) bonds.

$$K_2Cr_2O_7 + H_2SO_4 + 4H_2O_2 \rightarrow 2CrO_5 + K_2SO_4 + 5H_2O $$.


The oxidation state of $$Cr$$ in $$CrO_5$$ is +6.
Let $$X$$ be the oxidation state of $$Cr$$ in $$CrO_5$$.
$$X+(-2)+2(-2)=0$$
$$X=+6$$.

Hence, the correct option is $$C$$.


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