Single Choice

In the spectrum of hydrogen, the ratio of the longest wavelength in the Lyman series to the longest wavelength in the Balmer series is:

A$$\displaystyle \frac{5}{27}$$
Correct Answer
B$$\displaystyle \frac{4}{9}$$
C$$\displaystyle \frac{9}{4}$$
D$$\displaystyle \frac{27}{5}$$

Solution

Transition to $$n=1$$ and $$n=2$$ are refered to as Lyman and Balmer series.

For Lyman Series wavelength will be longest when energy the electron has transition from $$n=2$$ to $$n=1$$ level.
For Balmer Series wavelength will be longest when energy the electron has transition from $$n=3$$ to $$n=2$$ level.
$$E_2 -E_1 \propto (- \dfrac{1}{1^2} + \dfrac{1}{2^2} ) = \dfrac{3}{4}$$
$$E_3 -E_2 \propto (- \dfrac{1}{3^2} + \dfrac{1}{2^2} ) = \dfrac{5}{36}$$
$$\dfrac{E_2 -E_1 }{E_3 -E_2 } = \dfrac{\dfrac{3}{4}}{ \dfrac{5}{36}}=\dfrac{27}{5}$$
Hence, $$ \dfrac{\lambda _L } {\lambda _B}=\dfrac{5}{27}$$ as $$E \propto \dfrac{1}{\lambda}$$


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