Redox Reactions
Which of the following are primary standard?
KMnO4 acts as an oxidizing agent in acidic medium. The number of moles of KMnO4 that will be needed to react with one mole of sulphide ions in acidic solution is:
$$5\overline { e } +Mn{ O }_{ 4 }^{ -2 }\longrightarrow M{ n }^{ +2 }\times 2\\ +\quad \quad \quad { 5 }^{ -2 }+2\overline { e } \longrightarrow S\times 2\\ \_ \_ \_ \_ \_ \_ \_ \_ \_ \_ \_ \_ \_ \_ \_ \_ \\ 2Mn{ O }_{ 4 }^{ - }+5{ S }^{ -2 }\longrightarrow 2Mn^{ +2 }+5S$$
Divide reaction by $$5.$$
$$\cfrac { 2 }{ 5 } Mn{ O }_{ 4 }^{ - }+{ 5 }^{ -2 }\longrightarrow 2Mn^{ +2 }+5S$$
Hence $$1$$ mole of sulphide ions will require $$\cfrac { 2 }{ 5 } $$ moles of $$Mn{ O }_{ 4 }^{ - }$$ ions.
Which of the following are primary standard?
Choose the correct statement:
Give reasons: Carbon cannot reduce the oxides of Na or Mg.