Single Choice

Polarising action of $$Cd^{2+}$$ an anions is stronger than that of $$Ca^{2+}$$ because:

Athe charges of the ions are same
Btheir radii are same ($$Ca^{2+}$$ = 0.104 nm, $$Cd^{2+}=0.099$$ nm)
Cthe $$Ca^{2+}$$ ion has a noble-gas electron configuration, and the $$Cd^{2+}$$ ion has an 18 electron configuration in its outer shell
Correct Answer
Dall of the above

Solution

Polarising action of $$Cd^{2+}$$ on anion is stronger than that of $$Ca^{2+}$$ because the $$Ca^{2+}$$ ion has a noble-gas electron configuration, and the $$Cd^{2+}$$ ion, an 18 electron configuration of its outer shell. A cation with 18 valence electrons has more polarizing power than a cation with 8 valence electrons.

SIMILAR QUESTIONS

Chemical Bonding

Polarisation is the distortion of the shape of anion by an adjacently placed cation. Which of the following statement is correct?

Chemical Bonding

Which of the following has been arranged in order of increasing covalent character?

Chemical Bonding

Which compound among the following has more covalent character ?

Chemical Bonding

Amongst $$LiCl$$, $$RbCl$$, $$BeCl_2$$ and $$MgCl_2$$, the compounds with the greatest and the least ionic character, respectively are:

Chemical Bonding

Among the following, the maximum covalent character is shown by which compound?

Chemical Bonding

Among the following which one has the highest cation to anion size ratio?

Chemical Bonding

Arrange the below molecules in order of increasing ionic character.$$LiF$$ $$, \ \displaystyle K_{2}O $$, $$ \displaystyle N_{2} $$, $$ \displaystyle SO_{2} $$ and $$ \displaystyle ClF_{3} $$

Chemical Bonding

The correct order of the increasing covalent character of the following is:

Chemical Bonding

The bond length in $$LiF$$ will be:

Chemical Bonding

According to Fajan's rule, covalent bond is favoured by:

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