Haloalkanes and Haloarenes
The major product of the following reaction is :
Show by chemical equation how would you prepare the following from the indicated starting materials. Specify the regents in each steps of synthesis of: Hexachloroethane $$(C_2Cl_6)$$ from calcium carbide.
$$CaC_2+H_2O\rightarrow C_2H_2+Ca(OH)_2$$
$$C_2H_2\xrightarrow{Ni/H_2}CH_2-CH_3$$
$$CH_3-CH_2\xrightarrow[prolonged\,treatment]{Cl_2(excess)ligh}Cl_3C-CCl_3$$
Hexachloroethane
The major product of the following reaction is :
In the following reactions, identify the compounds A, B, C and D. i. $$PCl_5 + SO_2 \rightarrow A + B$$ ii. $$A + MeCOOH \rightarrow C + SO_2 + HCl$$ iii. $$2C + Me_2Cd \rightarrow 2D + CdCl_2$$
Compound $$(B)$$ is:
Compound $$(C)$$ is:
Compound $$(E)$$ is:
Both have $$( -COCH_3)$$ group, but haloform is formed in (a) only. Explain.