Single Choice

The weakest acid among the following?

A$$CH_{3}COOH$$
B$$CH_{3}CH_{2}OH$$
Correct Answer
C$$ClCH_{2}COOH$$
D$$FCH_{2}COOH$$

Solution

1. As $$+I$$ groups are attached to a carboxylic acid, the acidic nature decreases.

2. As the size of $$+I$$ groups increases, the acidity decreases proportionally. Whereas the $$-I$$ groups enhance the acidity.

3. As in alcohols, the acidity is dependent on the same factors in the same way but compared to carboxylic acids, alcohols are less acidic due to their weak alkoxide ion $$(RO-)$$.

4. As the aromatic groups are connected, the acidic nature is enhanced due to resonance. So an aromatic carboxylic acid is more acidic than its aliphatic counterpart.

5. The order of acidity therefore is,

$$C_6H_5CH_2COOH > FCH_2COOH > ClCH_2COOH > CH_3COOH > CH_3CH_2OH$$


SIMILAR QUESTIONS

Acids, Bases and Salts

Arrange the following compounds in increasing order of their property as indicated: $$CH_3CH_2CH(Br)COOH, CH_2CH(Br)CH_2COOH, (CH_3)_2CHCOOH$$ ( acid strength )

Acids, Bases and Salts

Give reason why strong acid and concentrated acid do not mean the same thing ?

Acids, Bases and Salts

Solution P has a PH of 13, solution Q had PH 6 and solution R has a PH of 2. Which solution : is a strong acid?

Acids, Bases and Salts

The correct order of acid strength is:

Acids, Bases and Salts

Which among the following is strongest acid?

Acids, Bases and Salts

The strength of an acid depends on its tendency to______

Acids, Bases and Salts

Which of the following is the strongest acid

Acids, Bases and Salts

The $$pKa$$ for acid $$A$$ is greater than $$pKa$$ for acid $$B$$. The strong acid is:

Acids, Bases and Salts

(i) A strong acid has a weak conjugate base (ii) An acid is an electron pair acceptor The above statements (i) and (ii)

Acids, Bases and Salts

Among the following acids, the weaker one is:

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