Single Choice

What happens when tertiary butyl alcohol is passed over heated copper at $$300^0$$C ?

ASecondary butyl alcohol is formed.
B2-Methylpropene is formed .
Correct Answer
C1-Butene is formed .
DButanal is formed.

Solution

Tertiary alcohol when passed over $$Cu$$ at $$300^{\circ}C$$ is dehydrated to alkene. $$CH_{ 3 }-{ \underset { \underset { C{ H }_{ 3 } }{ | } }{ \overset { \overset { C{ H }_{ 3 } }{ | } }{ C } } }-OH\ \overset { Cu,\ 300^{ 0 }C }{ \longrightarrow } CH_{ 3 }-{ \underset { \underset { C{ H }_{ 3 } }{ | } }{ \overset { \overset { C{ H }_{ 2 } }{ || } }{ C } } }$$ $$t-butyl\ alcohol \overset { Cu,\ 300^{ 0 }C }{ \longrightarrow } 2-methyl\ propene$$


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