Single Choice

Which is correct statement? As the s-character of a hybrid orbital decreases (I) The bond angle decreases (II) The bond strength increases (III) The bond length increases (IV) Size of orbital increases

A(I), (III) and (IV)
Correct Answer
B(II), (III) and (IV)
C(I) and (II)
DAll are correct

Solution

The statements (I), (III) and (IV) are correct.

As the s-character of a hybrid orbital decreases,

(I) the bond angle decreases. The bond angles for $$ sp $$, $$sp^{2}$$ and $$ sp^{3} $$ hybrid orbitals are $$180^{0}$$ , $$ 120^{0} $$ and $$109^{0}$$ respectively.

(II) the bond strength decreases. Triple bond ($$sp$$ hybridisation) is stronger than double bond ($$sp^{2}$$ hybridisation) which in turn is stronger than single bond ($$sp^{3}$$ hybridisation).

(III) the bond length increases. Triple bond ($$ sp $$ hybridisation) is shorter than double bond ($$sp^{2}$$ hybridisation) which in turn is shorter than single bond ($$sp^{3}$$ hybridisation).

(IV) the size of orbital increases. s orbital is smaller than p orbital. Hence, $$ sp $$ hybrid orbitals are smaller than $$sp^{2}$$ hybrid orbitals which in turn are smaller than $$sp^{3}$$ hybrid orbitals.

Hence , option A is correct .


SIMILAR QUESTIONS

Chemical Bonding

Which of the following statement is correct?

Chemical Bonding

State True or False. All the orbitals in a set of hybridised orbitals have the same shape and energy

Chemical Bonding

The structural formula of a compound is $$CH_3-CH=C=CH_2$$. The type pf hybridization at the four carbon atoms from left to right is?

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What is the hybridization of each carbon in $$H_2C=C=CH_2$$?

Chemical Bonding

Which of the following statements is true about hybridisation?

Chemical Bonding

Which of the following molecular species is/are having $$\pi_{2p}$$ as H.O.M.O. (highest occupied molecular orbital):

Chemical Bonding

Which of the following process is/are associated with change of hybridization of the underlined compound?

Chemical Bonding

In which compound vacant hybride orbital take part in bonding :

Chemical Bonding

In which of the following combination hybridisation of central atom (*) does not change ?

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