Organic Compounds Containing Nitrogen
The correct order of boiling points of the following isomeric amines is: $$C_4H_9NH_2.(C_2H_5)_2NH,\, C_2H_5N(CH_3)_2$$
Which of the following compounds has the lowest boiling point?
N,N-dimethylmethanamine will have the lowest boiling points as it cannot form hydrogen bonds.
Other amines can form hydrogen bonds and have higher boiling points.
Option D is correct.
The correct order of boiling points of the following isomeric amines is: $$C_4H_9NH_2.(C_2H_5)_2NH,\, C_2H_5N(CH_3)_2$$
The decreasing order of boiling points of ethyldimethylamine, n- butylamine and diethylamine is n - Butylamine > Diethylamine > Ethyldimethylamine. This trend of the boiling point can be explained as:
Give plausible explanation for each of the following: (i) Why are amines less acidic than alcohols of comparable molecular masses? (ii) Why do primary amines have higher boiling point than tertiary amines? (iii) Why are aliphatic amines stronger bases than aromatic amines?
The correct order of boiling points of the following isomeric amines is: $$C_4H_9NH_2.(C_2H_5)_2NH,\, C_2H_5N(CH_3)_2$$
The decreasing order of boiling points of ethyldimethylamine, n- butylamine and diethylamine is n - Butylamine > Diethylamine > Ethyldimethylamine. This trend of the boiling point can be explained as:
Tertiary amines have lowest boiling points amongst isomeric amines because:
Give plausible explanation for: Why do primary amines have higher boiling points than tertiary amines?
Which of the following is/are correct?
Give reasons for the following: Primary amines have higher boiling point than tertiary amines.
Account for the following: Although trimethylamine and n-propylamine have the same molecular weight, but the former boils at a lower temperature (276K) than the latter (322K). Explain why.