Single Choice

Ammoniated solutions of alkali metals are reducing agents due to the presence of free ammoniated or solvated electrons that can reduce: (I) $$O_{2} $$ to $$O_{2}^{2-} $$ (II) $$K_{2} [Ni(AN)_4] $$ to $$K_{4} [Ni(CN)_4] $$ (III) Aromatic ring (IV) Non-terminal alkyne Choose the correct code:

AIII and IV
BII and III
CI , II , III and IV
DI , III and IV
Correct Answer

Solution

$$M(s) + NH_{3} (l) \rightarrow M^{+} (NH_3)_x + \bar{e}. (NH_3)_y$$

Ammoniated $$e^{-} $$ responsible for blue colour and reducing character.
If Conc. of solution is increased then associated of solvated electrons get started hence, paramagnetism decreases and solution changes to bronze colour.

Hence, Option "D" is the correct answer.

SIMILAR QUESTIONS

s - block Elements (Alkali and Alkaline Earth Metals)

A solution of sodium metal in liquid ammonia acts as a strong reducing agent due to the presence of:

s - block Elements (Alkali and Alkaline Earth Metals)

Unreacted sodium metal can be removed from liquid ammonia safely by:

s - block Elements (Alkali and Alkaline Earth Metals)

Highly pure dilute solution of sodium in liquid ammonia :

s - block Elements (Alkali and Alkaline Earth Metals)

When an alkali metal dissolves in liquid ammonia the solution can acquire different colours. Explain the reasons for this type of colour change.

s - block Elements (Alkali and Alkaline Earth Metals)

The alkali metals dissolve in ammonia to give a deep blue solution which is conducting in nature. $$M +(x + y) NH_3 \rightarrow [M(NH_3)_x]^{2+} + 2[e(NH_3)y]^-$$ Which of the following is not true about the solutions are alkali metals in liquid ammonia?

s - block Elements (Alkali and Alkaline Earth Metals)

Select the correct statement(s):

s - block Elements (Alkali and Alkaline Earth Metals)

The alkali metals dissolve in liquid $$NH_3$$, it is found that :

s - block Elements (Alkali and Alkaline Earth Metals)

A solution of sodium in liquid ammonia is blue in colour due to:

s - block Elements (Alkali and Alkaline Earth Metals)

Which of the following statement about solution of alkali metals in liquid ammonia is correct ?

s - block Elements (Alkali and Alkaline Earth Metals)

Which of the following metal(s) in liquid $$NH_{3} $$ with low conc. is not paramagnetic ?

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