Electrochemistry
A current of $$ 5 $$ ampere is flowing through a wire for $$ 193 $$ seconds . Calculate the number of electrons flowing through the cross section of wire for $$ 193 $$ seconds .
Calculate the number of electrons lost or gained during electrolysis of : $$ (a) \, 2g \,Br^{-} $$ ions , $$ (b)\, 1g \,Cu^{2+} $$ ions .
(a) Eq. of $$ Br $$ used = $$ \dfrac{2}{80} $$ for $$ 2Br^- \rightarrow Br_2 + 2e $$
$$ \because $$ $$ 1 $$ eq. of an element involve = $$ 1 $$ Faraday charge
$$ = 6.023 \times 10^{23} $$ electrons
$$ \therefore $$ $$ \dfrac{2}{80} $$ eq. of $$ Br^- $$ involve $$ = \dfrac{6.023\times 10^{23} \times 2}{80} $$
$$ = 1.51 \times 10^{22} $$ electrons lost
(b) Similarly , calculate for $$ Cu^{2+} + 2e \rightarrow Cu $$
No. of electrons gained = $$ 1.89 \times 10^{22} $$
A current of $$ 5 $$ ampere is flowing through a wire for $$ 193 $$ seconds . Calculate the number of electrons flowing through the cross section of wire for $$ 193 $$ seconds .
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The electrochemical cell given alongside converts the chemical energy released during the redox reaction . $$ Zn(s) + Cu^{2+} (aq) \rightarrow Zn^{2+}(aq) + Cu(s) $$ to electrical energy . It gives an electrical potential of $$ 1.1\,V $$ when concentration $$ Zn^{2+} $$ and $$ Cu^{2+} $$ ions is unity . State the direction of flow of current and also specify whether zinc and copper are deposited of dissolved at their respective electrodes when : An external opposite potential of less than $$ 1.1 \,V $$ is applied .
The electrochemical cell given alongside converts the chemical energy released during the redox reaction . $$ Zn(s) + Cu^{2+} (aq) \rightarrow Zn^{2+}(aq) + Cu(s) $$ to electrical energy . It gives an electrical potential of $$ 1.1\,V $$ when concentration $$ Zn^{2+} $$ and $$ Cu^{2+} $$ ions is unity . State the direction of flow of current and also specify whether zinc and copper are deposited of dissolved at their respective electrodes when : An external potential of $$ 1.1 \,V $$ is applied .
The electrochemical cell given alongside converts the chemical energy released during the redox reaction . $$ Zn(s) + Cu^{2+} (aq) \rightarrow Zn^{2+}(aq) + Cu(s) $$ to electrical energy . It gives an electrical potential of $$ 1.1\,V $$ when concentration $$ Zn^{2+} $$ and $$ Cu^{2+} $$ ions is unity . State the direction of flow of current and also specify whether zinc and copper are deposited of dissolved at their respective electrodes when : An external potential of greater than $$ 1.1 \,V $$ is applied .
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