Subjective Type

Comment upon acidic character of terminal alkynes.

Solution

The acidity of a terminal alkyne is due to the high level of s character in the sp hybrid orbital, which bonds with the s orbital of the hydrogen atom to form a single covalent bond. The high level of s character in an sp‐hybridized carbon causes the overlap region of the σ bond to shift much closer to the carbon atom. This polarizes the bond, causing the hydrogen atom to become slightly positive. This slight positive charge makes the hydrogen atom a weak proton, which can be removed by a strong base.


SIMILAR QUESTIONS

Hydrocarbons

The correct order for acid strength of compounds $$CH\equiv CH, CH_{3}-C \equiv CH$$ and $$CH_{2} = CH_{2}$$ is as follows:

Hydrocarbons

Which of the following does not give a white precipitate with $$AgNO_3$$ solution?

Hydrocarbons

Which of the following has acidic hydrogen?

Hydrocarbons

The hydrocarbon which can react with sodium in liquid ammonia is:

Hydrocarbons

Fill in the blanks: The carbon atoms of ethyne are ______ hybridized.

Hydrocarbons

Fill in the blanks: A compound of carbon and hydrogen used for welding purposes is ______.

Hydrocarbons

Fill in the blanks: Carbon atoms in $$Ag_{2}C_{2}$$ (silver acetylide) are ________ hybridized.

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