Subjective Type

"$$He_2$$ does not exist since its bond-order is zero." Answer whether the above statement is true or false.

Solution

$$He_2$$ has MO electronic configuration as $$\underset {bonding}{\sigma1s^2}\ \underset{Anti-bonding}{{\sigma}^*1s^2}$$ Bond order $$=\cfrac{N_B-N_A}{2}= (2-2)/2=0$$ Thus, electron and Bond − But $$He^+$$ ion exists, as it has a configuration of $$\underset {bonding}{\sigma1s^2}\ \underset{Anti-bonding}{{\sigma}^*1s^1}$$ Bond order $$=\cfrac{N_B-N_A}{2}=\cfrac{2-1}{2}$$ As bond order is positive $$He^+$$ exists. Due to one unpaired electron $$He_2^+$$ is paramagnetic. The statement is true.


SIMILAR QUESTIONS

Chemical Bonding

Which of the following does not exist?

Chemical Bonding

The bond order of $$NO$$ is $$2.5$$ while that of $$NO^{+}$$ is $$3$$. Which of the following statements is true for these two species?

Chemical Bonding

The correct order of bond dissociation energy among $$N_2,\ O_2,\ O_2^-$$ is shown in which of the following arrangements?

Chemical Bonding

Which of the following pairs have identical values of bond order?

Chemical Bonding

Bond order of $$O_2, O_2^+, O_2^-$$ and $$O_2^{2-}$$ is in order________.

Chemical Bonding

The bond order and the magnetic characteristics of $$\text {CN}^-$$ are:

Chemical Bonding

Using MO theory, predict which of the following species has the shortest bond length?

Chemical Bonding

Among the following molecules/ions, $$C^{2-}_2, N^{2-}_2, O^{2-}_2, O_2$$ which one is diamagnetic and has the shortest bond length?

Chemical Bonding

Among the following, the molecule expected to be stabilized by anion formation is: $${C}_{2},{O}_{2},NO,{F}_{2}$$

Chemical Bonding

During the change of $$O_2$$ to $$O_2^-$$, the incoming electrons goes to the orbital:

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