True / False

State True or False. $$O_2, O_2^-$$ and $$O_2^{2-}$$ are paramagnetic species.

ATRUE
BFALSE
Correct Answer

Solution

The given statement is False.
$$\displaystyle O_2$$ and $$\displaystyle O_2^-$$ are paramagnetic while $$\displaystyle O_2^{2-}$$ is diamagnetic.

If unpaired electrons are present in an ion/molecule, then it is paramagnetic.
If all electrons are paired, then the ion/molecule is diamagnetic

The MO electronic configurations are given.
$$\displaystyle O_2 : KK (\sigma 2s)^2(\sigma * 2s)^2 (\sigma 2px)^2 (\pi 2py)^2 (\pi 2pz)^2 (\pi * 2py)^1 (\pi * 2pz)^1 $$ 2 unpaired electrons.

$$\displaystyle O_2^- : KK (\sigma 2s)^2(\sigma * 2s)^2 (\sigma 2px)^2 (\pi 2py)^2 (\pi 2pz)^2 (\pi * 2py)^2 (\pi * 2pz)^1 $$ 1 unpaired electron.

$$\displaystyle O_2^{2-} : KK (\sigma 2s)^2(\sigma * 2s)^2 (\sigma 2px)^2 (\pi 2py)^2 (\pi 2pz)^2 (\pi * 2py)^2 (\pi * 2pz)^2 $$ 0 unpaired electrons.


SIMILAR QUESTIONS

Chemical Bonding

The most electronegative element is:

Chemical Bonding

The number of antibonding electron pairs in $$O^{2-}_{2}$$ molecular ion on the basis of molecular orbital theory is :

Chemical Bonding

Which of the following species are paramagnetic?

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Among $$KO_2, AlO_2^-, BaO_2, and NO_2^+$$, unpaired electron is present in:

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The total number of bonding and antibonding electrons in $$\displaystyle O{_{2}}^{+}$$ are respectively. (If the answer is 14 and 7, then represent as 0147):

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Which of the following molecules is expected to exhibit diamagnetic behaviour?

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The pairs of species of oxygen and their magnetic behaviours are noted below. Which of the following presents the correct description ?

Chemical Bonding

Which of the following is paramagnetic?

Chemical Bonding

During change of $${O}_{2}$$ to $${O}_{2}^{-}$$ ion, the electron adds on which one of the following orbitals?

Chemical Bonding

When $$O_2$$ is absorbed on a metallic surface, electron transfer occurs from the metal to $$O_2$$. The true statement(s) regarding this adsorption is(are):

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