Chemical Bonding
The most electronegative element is:
When $$O_2$$ is absorbed on a metallic surface, electron transfer occurs from the metal to $$O_2$$. The true statement(s) regarding this adsorption is(are):
When $$O_2$$ is adsorbed on a metallic surface, electron transfer occurs from the metal to $$O_2$$.
The MO configuration of $$O_2$$ is $$KK(\sigma 2s)^2(\sigma ^* 2s)^2(\sigma 2p_x)^2(\pi 2p_y)^2(\pi 2p_z)^2(\pi ^* 2p_y)^1(\pi ^* 2p_z)^1$$
The MO configuration of $$O_2^-$$ is $$KK(\sigma 2s)^2(\sigma ^* 2s)^2(\sigma 2p_x)^2(\pi 2p_y)^2(\pi 2p_z)^2(\pi ^* 2p_y)^2(\pi ^* 2p_z)^1$$
(A) Thus, oxygen is chemisorbed. Hence, the statement (A) is false.
(B) Chemisorption is an exothermic process. Heat is released. Hence, the statement (B) is true.
(C) The occupancy of $$ \pi ^*_{2p}$$ of $$O_2$$ is increased. The added electron enters $$\pi ^* _{2p_y}$$ MO. Hence, the statement (C) is true.
(D) The bond order is decreased (as the electron enters anti bonding MO) and the bond length of $$O_2$$ is increased. Hence, the statement (D) is true.
The most electronegative element is:
The number of antibonding electron pairs in $$O^{2-}_{2}$$ molecular ion on the basis of molecular orbital theory is :
Which of the following species are paramagnetic?
Among $$KO_2, AlO_2^-, BaO_2, and NO_2^+$$, unpaired electron is present in:
The total number of bonding and antibonding electrons in $$\displaystyle O{_{2}}^{+}$$ are respectively. (If the answer is 14 and 7, then represent as 0147):
State True or False. $$O_2, O_2^-$$ and $$O_2^{2-}$$ are paramagnetic species.
Which of the following molecules is expected to exhibit diamagnetic behaviour?
The pairs of species of oxygen and their magnetic behaviours are noted below. Which of the following presents the correct description ?
Which of the following is paramagnetic?
During change of $${O}_{2}$$ to $${O}_{2}^{-}$$ ion, the electron adds on which one of the following orbitals?