Haloalkanes and Haloarenes
$$CH_3-\underset{CH_3}{\underset{|}{\overset{CH_3\!\!\!\!\!\!}{\overset{|}{C}}}-}CH_2-\overset{CH_3}{\overset{|}{C}H}-CH_3$$ $$\xrightarrow{Br_2/hu}$$
For the given reaction how many products are optically active (all isomers) :
Haloalkanes and Haloarenes
Which one of the following compounds is not optically active?
Haloalkanes and Haloarenes
An optically active alcohol $$A(C_{6}H_{10}O)$$ absorbs $$2mol$$ of hydrogen per mole of $$A$$ upon catalytic hydrogenation and gives a product $$B$$. The compound $$B$$ is resistent to oxidation by $$CrO_{3}$$ and does not show any optical activity. Deduce the structures of $$A$$ and $$B$$.
Haloalkanes and Haloarenes
An optically active compound:
Haloalkanes and Haloarenes
Give the stereochemical products of the following.
Haloalkanes and Haloarenes
Which statement is correct about the above reaction?
Haloalkanes and Haloarenes
If both compounds (A) and (B) are optically active,the possible structures of (B) are
Haloalkanes and Haloarenes
The compounds are optically inactive because
Haloalkanes and Haloarenes
An acidic compound $$(A)$$. $$({C}_{4}{H}_{8}O)$$ loses its optical activity on strong heating yielding $$(B)$$ $$({C}_{4}{H}_{6}{O}_{2})$$ which reacts readily with $$KMn{O}_{4}$$. $$(B)$$ forms a derivative $$(C)$$ with $$SO{Cl}_{2}$$ which on reaction with $${({CH}_{3})}_{2}NH$$ gives $$(D)$$. The compound $$(A)$$ on oxidation with dilute chromic acid gives an unstable compound $$(E)$$ which decaboxylates readily to give $$(F)$$ ($${C}_{3}{H}_{6}O$$). The compound $$(F)$$ gives a hydrocarbon $$(G)$$ on treatment with amalgamated $$Zn$$ and $$HCl$$. Give the structures of $$(A)$$ to $$(G)$$ with proper reasoning.
Haloalkanes and Haloarenes
Compound $$(E)$$ is