Solutions
If Raoult's law is obeyed, then vapour pressure of the solvent in a solution is directly proportional to:
The relative lowering of the vapour pressure is equal to the ratio between the number:
Relative Lowering of the vapour pressure of the solvent:
When a non-volatile solute is added to a solvent, the vapour pressure of the solution decreases.
According to Raoult's Law, the vapour pressure of a solvent (P1) in a solution containing a non-volatile solute is given by
P1=x1P
°
1
Vapour pressure of the pure solvent = P
°
1
Vapour pressure of the solvent in solution = P1
ΔP1=P1°−P1
=P1°−x1P1°
=P1°(1−x1)
In a binary solution, 1−x1=x2
ΔP1=P1°x2
ΔP1/P1°=(P1°−P1)/P1°=x2
The lowering of vapour pressure relative to the vapour pressure of the pure solvent is called a relative lowering of vapour pressure.
ΔP1/P1° → Relative lowering of Vapour pressure
Thus, the relative lowering in vapour pressure depends only on the concentration of solute particles and is independent of their identity.
If Raoult's law is obeyed, then vapour pressure of the solvent in a solution is directly proportional to:
The weight of an empty china dish is 39 g and when a saturated solution of potassium nitrate is poured into, its weight is 108 g at $$50^{\circ}C$$. After evaporating the solution to dryness, if the weight of the dish along with the crystals is 72 g then the solubility of potassium nitrate at $$50^{\circ} C$$ is .....................
For a dilute solution, Raoult's law states that:
Which one of the following is incorrect for ideal solution?
The mixture which shows positive deviation from Raoult’s law is
For a dilute solution, Raoult's law states that:
Which of the following is satisfied by an ideal solution?
What are the similarities between Raoult's Law and Henry's Law
State the following : Raoult's law in its general form in reference to solutions .
State Raoult's law for the solution containing volatile components. Write two differences between an ideal solution and a non-ideal solution.