d - block and f - block Elements
The transition elements have
Explain: The enthalpies of atomisation of transition metals are quite high.
This is because transition metals have strong metallic bonds as they have large number of unpaired electrons.
The transition elements have
Why first ionization enthalpy of $$Cr$$ is less than that of $$Zn$$?
Ionization enthalpies of $$Ce, Pr $$ and $$Nd$$ are higher than $$Th, Pa$$ and $$U$$. Why?
Give reason for: Transition metals have high enthalpies for atomisation.
Give reason: The $$E^{\circ}$$ value for the $$Mn^{3+}|Mn^{2+}$$ couple is much more positive than that for $$Cr^{3+}|Cr^{2+}$$ couple or $$Fe^{3+}|Fe^{2+}$$ couple.
Give reason: The enthalpies of atomisation of transition elements are high.
The elements of 3d transition series are given as: $$Sc$$ $$Ti$$ $$V$$ $$Cr$$ $$Mn$$ $$Fe$$ $$Co$$ $$Ni$$ $$Cu$$ $$Zn$$ Copper has exceptionally positive $$E_{M^{2+}/M}^{\circ}$$ value. Why?
Account for: $$E^{\circ}_{M^{2+}/M}$$ values for transition metals show irregular variation.
Which of the following has second ionisation potential less than expected?
Ionisation potential values of d-block elements as compared to ionization potential value of f-block elements are