d - block and f - block Elements
Why first ionization enthalpy of $$Cr$$ is less than that of $$Zn$$?
The transition elements have
Transition elements have $$(I)$$ Partly filled d-orbitals and completely filled higher s-orbitals.eg $$Ti(Z=22):[Ar]{3d}^{2},{4s}^{2}$$ $$(II)$$ Completely filled d-orbitals and partly filled higher s-orbitals eg. $$Ag(Z=47):[Kr]{4d}^{10},{5s}^{1}$$ $$(III)$$ Completely filled d-orbitals and completely filled s-orbitals eg, $$Zn(Z=30): [Ar]{3d}^{10},{4s}^{2}$$
Why first ionization enthalpy of $$Cr$$ is less than that of $$Zn$$?
Ionization enthalpies of $$Ce, Pr $$ and $$Nd$$ are higher than $$Th, Pa$$ and $$U$$. Why?
Give reason for: Transition metals have high enthalpies for atomisation.
Give reason: The $$E^{\circ}$$ value for the $$Mn^{3+}|Mn^{2+}$$ couple is much more positive than that for $$Cr^{3+}|Cr^{2+}$$ couple or $$Fe^{3+}|Fe^{2+}$$ couple.
Give reason: The enthalpies of atomisation of transition elements are high.
Explain: The enthalpies of atomisation of transition metals are quite high.
The elements of 3d transition series are given as: $$Sc$$ $$Ti$$ $$V$$ $$Cr$$ $$Mn$$ $$Fe$$ $$Co$$ $$Ni$$ $$Cu$$ $$Zn$$ Copper has exceptionally positive $$E_{M^{2+}/M}^{\circ}$$ value. Why?
Account for: $$E^{\circ}_{M^{2+}/M}$$ values for transition metals show irregular variation.
Which of the following has second ionisation potential less than expected?
Ionisation potential values of d-block elements as compared to ionization potential value of f-block elements are