d - block and f - block Elements
The transition elements have
Which of the following has second ionisation potential less than expected?
Zn has second ionisation potential less than expected due to increased shielding effect the attraction of electrons towards the nucleus decreases.
The transition elements have
Why first ionization enthalpy of $$Cr$$ is less than that of $$Zn$$?
Ionization enthalpies of $$Ce, Pr $$ and $$Nd$$ are higher than $$Th, Pa$$ and $$U$$. Why?
Give reason for: Transition metals have high enthalpies for atomisation.
Give reason: The $$E^{\circ}$$ value for the $$Mn^{3+}|Mn^{2+}$$ couple is much more positive than that for $$Cr^{3+}|Cr^{2+}$$ couple or $$Fe^{3+}|Fe^{2+}$$ couple.
Give reason: The enthalpies of atomisation of transition elements are high.
Explain: The enthalpies of atomisation of transition metals are quite high.
The elements of 3d transition series are given as: $$Sc$$ $$Ti$$ $$V$$ $$Cr$$ $$Mn$$ $$Fe$$ $$Co$$ $$Ni$$ $$Cu$$ $$Zn$$ Copper has exceptionally positive $$E_{M^{2+}/M}^{\circ}$$ value. Why?
Account for: $$E^{\circ}_{M^{2+}/M}$$ values for transition metals show irregular variation.
Ionisation potential values of d-block elements as compared to ionization potential value of f-block elements are