Chemical Bonding
Odd electron bond is present in:
If the magnetic moment of a dioxygen species is 1.73 BM, it may be:
$$\mu = \sqrt{n(n+2)} = 1.73\ B.M$$
$$\therefore \sqrt{n(n+2)} = 1.73$$
$$\therefore (\sqrt{n(n+2)})^2 = (1.73)^2$$
$$\therefore n(n+2) = 3$$
$$n = 1$$
$$\therefore$$ One unpaired electron
In option B:
$${O_2}^-$$ has $$17$$ electrons.
$$\sigma 1s^2 \sigma^*1s^2\ \ \sigma\ 2s^2\sigma^*2s^2\ \ \sigma 2{p_z}^2\ \ \pi 2{p_x}^2 = \pi 2{p_y}^2\ \ \ \pi^* 2{p_x}^2 = \pi^*2{p_y}^1$$
$$\Rightarrow$$ One unpaired electron
$${O_2}^+$$ has 15 electrons.
$$\sigma 1s^2 \sigma^*1s^2\ \ \sigma\ 2s^2\sigma^*2s^2\ \ \sigma 2{p_z}^2\ \ \pi 2{p_x}^2 = \pi 2{p_y}^2\ \ \ \pi^* 2{p_x}^1 = \pi^*2{p_y}^0$$
$$\Rightarrow $$ One unpaired electron
$$\therefore {O_2}^-$$ & $${O_2}^{+}$$ both of the species contain one unpaired electron. i.e, $$n = 1$$.
Hence, option $$B$$ is correct.
Odd electron bond is present in:
Which is paramagnetic and coloured?
What is the magnetic moment of $$[FeF_6]^{3-}$$?
The paramagnatic property of the oxygen molecule due to the presence of unpaired electrons present in:
Chloro compound of vanadium has only spin magnetic moment of $$1.73\ BM$$. This vanadium chloride has the formula: [Atomic number of $$V=23$$]
Which one of the following molecules is paramagnetic?
Which of the following species is not paramagnetic ?
Which one of the following property is not shown by $$NO$$?
Magnetic moment $$2.84\ BM$$ is given by : (Atomic numbers : $$Ni=28, Ti=22, Cr=24, Co=27)$$
The pair(s) of reagents that yield paramagnetic species is/are: