Single Choice

Solubility of the alkaline earth's metal sulphates in water decreases in the sequence :

A$$Sr > Ca > Mg > Ba$$
B$$Ba > Mg > Sr > Ca$$
C$$Mg > Ca > Sr > Ba$$
Correct Answer
D$$Ca > Sr > Ba > Mg$$

Solution

The solubility of the alkaline earth's metal sulphates in water decreases in the sequence $$Mg > Ca > Sr > Ba$$.

With the increase in the cationic size on moving down the group, the extent of the hydration of the cation decreases. However, the decrease in the lattice energy with increase in cationic size is small.

Thus, the decrease in hydration energy is more significant than the decrease in lattice energy. Hence, the solubility of the alkaline earth's metal sulphates in water decreases on moving down the group.


SIMILAR QUESTIONS

s - block Elements (Alkali and Alkaline Earth Metals)

In the following table are given eight elements, $$A, B, C, D, E, F, G$$ and $$H$$ (here letters are not the usual symbols of the elements) of the Modern Periodic Table with the atomic numbers of the elements in parenthesis. Period Group $$1$$ Group $$2$$ $$2$$ $$A(3)$$ $$E(4)$$ $$3$$ $$B(11)$$ $$F(12)$$ $$4$$ $$C(19)$$ $$G(20)$$ $$5$$ $$D(37)$$ $$H(38)$$ Out of the three elements $$B, E,$$ and $$F$$, which one has the biggest atomic size?

s - block Elements (Alkali and Alkaline Earth Metals)

The metal carbonate which decomposes easily on heating is:

s - block Elements (Alkali and Alkaline Earth Metals)

Which of the following does not exist in solid state?

s - block Elements (Alkali and Alkaline Earth Metals)

The compound insoluble in acetic acid is :**

s - block Elements (Alkali and Alkaline Earth Metals)

The correct order of the solubility of alkaline-earth metal sulphates in water is:

s - block Elements (Alkali and Alkaline Earth Metals)

Which one of the following alkaline earth metal sulphates has its hydration enthalpy greater than its lattice enthalpy?

s - block Elements (Alkali and Alkaline Earth Metals)

The decomposition temperature is maximum for:

s - block Elements (Alkali and Alkaline Earth Metals)

On heating which of the following $$CO_2$$ releases most easily?

s - block Elements (Alkali and Alkaline Earth Metals)

Which one of the following alkaline earth metal carbonates is thermally the most stable?

s - block Elements (Alkali and Alkaline Earth Metals)

Which of the following will have lowest value of $$K_{sp}$$ at room temperature?

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