Coordination Compounds
The extent of crystal field splitting in octahedral complex of the given metal with particular weak field ligand are such that :
The complex that has the highest crystal splitting energy $$(\Delta)$$, is:
Crystal Field Theory -
According to this theory, metal and ligand are considered as point charges. This theory deals with electrostatic force of attraction means the talks about the ionic character of M-L bond.
As complex $$K_3[Co(CN)_6]$$ have $$CN^-$$ ligand which is strongfield ligand amongst the given ligand in other complexes.
The extent of crystal field splitting in octahedral complex of the given metal with particular weak field ligand are such that :
Define crystal field splitting energy.
On the basis of crystal field theory, write the electronic configuration for $$d^{4}$$ ion, if $$\Delta_0 > P$$
Geometrical shapes of the complexes formed by the reaction of $$Ni^{2+}$$ with $$Cl^{-},\ CN^{-}$$ and $$H_{2}O$$, respectively, are:
A metal ion $$M^{n+}$$ having $$d^4$$ valence electronic configuration combines with three bidentate ligands to form a compound. Assuming $$\Delta_0 > P$$: Explain orbital splitting during this complex formation.
Geometrical shapes of the complexes formed by the reaction of $$Ni^{2+}$$ with $$Cl^{-},\ CN^{-}$$ and $$H_{2}O$$, respectively, are:
Select the correct order of magnetic moment (in B.M.) from the following options :
The increasing order of the crystal field splitting power of some common ligands is?
In which of the following complexes of the Co (atomic no. $$=27$$), will the magnitude of $$\Delta_o$$ be the highest?