Single Choice

The false statements among the following are: I. A primary carbocation is less stable than a tertiary carbocation. II. A cyclopropyl methyl carbocation is less stable than allyl carbocation. III. A tertiary free radical is more stable than a primary free radical. IV. Isopropyl carbanion is more stable than ethyl carbanion.

AI and II
BII and III
CI and IV
DII and IV
Correct Answer

Solution

Since cyclopropyl methyl carbocation (dancing resonance) is exceptionally more stable than allyl carbocation and ethyl carbanion is more stable than isopropyl carbanion. Rest other statements are correct. Tertiary free radical is more stable than a primary free radical due to $$+I$$ effect of three methane. Same is the case with carbocations.


SIMILAR QUESTIONS

Organic Chemistry

Select the correct statement about carbonium ion, $$\overset{\oplus}{C}H_5$$

Organic Chemistry

Arrange the carbanions, $$(\mathrm{C}\mathrm{H}_3)_{3}\overline{\mathrm{C}},\overline{\mathrm{C}}\mathrm{C}l_{3},(\mathrm{C}\mathrm{H}_3)_{2}\overline{\mathrm{C}}\mathrm{H},\ \mathrm{C}{}_{6}\mathrm{H}_{5}\overline{\mathrm{C}}\mathrm{H}_{2}$$ , in order of their decreasing stability:

Organic Chemistry

Which one of the following substituents at para-position is most effective in stabilizing the phenoxide ion?

Organic Chemistry

Which of the following statement is not true about carbanions?

Organic Chemistry

Which of the following is cabanion expected to be most stable?

Organic Chemistry

The order of decreasing stability of the following carbanion is: (i) $${ (C{ H }_{ 3 }) }_{ 3 }C^- $$ (ii) $$C{ { H }_{ 3 } } ^-$$ (iii) $${ C{ H }_{ 3 } }C { }{ { H }_{ 2 } } ^-$$ (iv) $${ (C{ H }_{ 3 }) }_{ 2 }C{ H } ^-$$

Organic Chemistry

Arrange the following carbanions in order of their decreasing stability. (I) $$H_3C-C\equiv C^-$$ (II) $$ H-C \equiv C^-$$ (III) $$ H_3C-CH^-_2$$

Organic Chemistry

Give the order of stabilities of the following : a. $$ Ph_3 \dot {C} $$ b. $$ Ph \dot{ C}H_2 $$ c. $$ Me_3 \dot {C} $$ d. $$ \dot {C_2}H_5 $$ e. $$ \dot {CH_3} $$

Organic Chemistry

Give the order of stabilities of the following : b. Ph3C⊖ c.Me2CH⊖ d.C⊖H3 e.C ⊖ 2 H5 f.Me3C⊖

Contact Details