Organic Chemistry
Select the correct statement about carbonium ion, $$\overset{\oplus}{C}H_5$$
The false statements among the following are: I. A primary carbocation is less stable than a tertiary carbocation. II. A cyclopropyl methyl carbocation is less stable than allyl carbocation. III. A tertiary free radical is more stable than a primary free radical. IV. Isopropyl carbanion is more stable than ethyl carbanion.
Since cyclopropyl methyl carbocation (dancing resonance) is exceptionally more stable than allyl carbocation and ethyl carbanion is more stable than isopropyl carbanion. Rest other statements are correct. Tertiary free radical is more stable than a primary free radical due to $$+I$$ effect of three methane. Same is the case with carbocations.
Select the correct statement about carbonium ion, $$\overset{\oplus}{C}H_5$$
Arrange the carbanions, $$(\mathrm{C}\mathrm{H}_3)_{3}\overline{\mathrm{C}},\overline{\mathrm{C}}\mathrm{C}l_{3},(\mathrm{C}\mathrm{H}_3)_{2}\overline{\mathrm{C}}\mathrm{H},\ \mathrm{C}{}_{6}\mathrm{H}_{5}\overline{\mathrm{C}}\mathrm{H}_{2}$$ , in order of their decreasing stability:
Which one of the following substituents at para-position is most effective in stabilizing the phenoxide ion?
Which of the following statement is not true about carbanions?
Which of the following is cabanion expected to be most stable?
The order of decreasing stability of the following carbanion is: (i) $${ (C{ H }_{ 3 }) }_{ 3 }C^- $$ (ii) $$C{ { H }_{ 3 } } ^-$$ (iii) $${ C{ H }_{ 3 } }C { }{ { H }_{ 2 } } ^-$$ (iv) $${ (C{ H }_{ 3 }) }_{ 2 }C{ H } ^-$$
Arrange the following carbanions in order of their decreasing stability. (I) $$H_3C-C\equiv C^-$$ (II) $$ H-C \equiv C^-$$ (III) $$ H_3C-CH^-_2$$
Give the order of stabilities of the following : a. $$ Ph_3 \dot {C} $$ b. $$ Ph \dot{ C}H_2 $$ c. $$ Me_3 \dot {C} $$ d. $$ \dot {C_2}H_5 $$ e. $$ \dot {CH_3} $$
Give the order of stabilities of the following : b. Ph3C⊖ c.Me2CH⊖ d.C⊖H3 e.C ⊖ 2 H5 f.Me3C⊖
The most stable carbanion is :