Organic Chemistry
Shifting of electrons of multiple bonds under the influence of a reagent is called__________.
Polarisation of electrons in acrolein may be written as :
Polarisation of electrons in acrolein may be written as $$\overset { +\delta }{ C } { H }_{ 2 }=CH-CH=\overset { -\delta }{ O }$$.
O atom is more EN than C atom, so it acquires $$\left(-\delta\right)$$ charge and C atom acquires $$\left(+\delta\right)$$ charge which is transferred to the last C atom.
Shifting of electrons of multiple bonds under the influence of a reagent is called__________.
The displacement of electrons in a multiple bond in the presence of attacking reagent is called:
The electromeric effect in organic compounds is a:
Explain the terms Inductive and Electromeric effects. Which electron displacement effect explains the following correct orders of acidity of the carboxylic acids? $$Cl_3CCOOH> Cl_2CHCOOH> ClCH_2COOH$$
Explain the terms Inductive and Electromeric effects. Which electron displacement effect explains the following correct orders of acidity of the carboxylic acids? $$CH_3CH_2COOH> (CH_3)_2CHCOOH> (CH_3)_3CCOOH$$
Fill in the blanks : The kind of delocalisation involving sigma bond orbitals is called ..............
Fill in the blanks: Electromeric effect is a _______ effect in which ________ of electrons takes place from one atom to the other joined by a ________ bond.
Explain inductive and electromeric effect with examples.
Electromeric effect.
Which of the following hydrogens is most easily abstracted on reaction with bromine?