Organic Chemistry
The displacement of electrons in a multiple bond in the presence of attacking reagent is called:
Shifting of electrons of multiple bonds under the influence of a reagent is called__________.
Electromeric effect refers to a molecular polarizability effect occurring by an intramolecular electron displacement (sometimes called the conjugative mechanism and, previously, the tautomeric mechanism) characterized by the substitution of one electron pair for another within the same atomic octet of electrons.
This effect is shown by those compounds containing multiple bonds. When a double or a triple bond is exposed to an attack by a reagent, a pair of bonding electrons involved in the $$\pi$$ bond is transferred completely from one atom to another.
This effect will remain as long as the attacking reagent is present. As soon as the reagent is removed, the polarized molecule will come back to the original state.
Option C is correct.
The displacement of electrons in a multiple bond in the presence of attacking reagent is called:
The electromeric effect in organic compounds is a:
Explain the terms Inductive and Electromeric effects. Which electron displacement effect explains the following correct orders of acidity of the carboxylic acids? $$Cl_3CCOOH> Cl_2CHCOOH> ClCH_2COOH$$
Explain the terms Inductive and Electromeric effects. Which electron displacement effect explains the following correct orders of acidity of the carboxylic acids? $$CH_3CH_2COOH> (CH_3)_2CHCOOH> (CH_3)_3CCOOH$$
Polarisation of electrons in acrolein may be written as :
Fill in the blanks : The kind of delocalisation involving sigma bond orbitals is called ..............
Fill in the blanks: Electromeric effect is a _______ effect in which ________ of electrons takes place from one atom to the other joined by a ________ bond.
Explain inductive and electromeric effect with examples.
Electromeric effect.
Which of the following hydrogens is most easily abstracted on reaction with bromine?