Organic Chemistry
Shifting of electrons of multiple bonds under the influence of a reagent is called__________.
Explain the terms Inductive and Electromeric effects. Which electron displacement effect explains the following correct orders of acidity of the carboxylic acids? $$Cl_3CCOOH> Cl_2CHCOOH> ClCH_2COOH$$
Inductive effect is the displacement of sigma electrons towards more electronegative species. It is transmuted though a chain of C atoms. It is classified into +I effect and -I effect.
Electron releasing groups such as alkyl groups show +I effect. -I effect is shown by electron withdrawing groups such as nitro, cyano, halo, amino etc.
Electromeric effect is temporary effect and involves transfer of pi electrons by the demand of attacking reagents towards more electronegative species.It is more powerful than inductive effect and is shown by compounds having C=C, C=N or $$N \equiv N$$ groups. It is classified into + E effect and -E effect.
In +E effect, pi electrons are transferred towards the attacking reagent whereas in -E effect, pi electrons are transferred away from the attacking reagent.
The decreasing order of the acidity $$\displaystyle Cl_3CCOOH> Cl_2CHCOOH> ClCH_2COOH $$ is explained on the following basis.
Electron withdrawing groups such as Cl, disperses the negative charge over the molecule and increases its stability and acidic nature. Hence, more is the number of electron withdrawing groups, more is the acidic nature.
Shifting of electrons of multiple bonds under the influence of a reagent is called__________.
The displacement of electrons in a multiple bond in the presence of attacking reagent is called:
The electromeric effect in organic compounds is a:
Explain the terms Inductive and Electromeric effects. Which electron displacement effect explains the following correct orders of acidity of the carboxylic acids? $$CH_3CH_2COOH> (CH_3)_2CHCOOH> (CH_3)_3CCOOH$$
Polarisation of electrons in acrolein may be written as :
Fill in the blanks : The kind of delocalisation involving sigma bond orbitals is called ..............
Fill in the blanks: Electromeric effect is a _______ effect in which ________ of electrons takes place from one atom to the other joined by a ________ bond.
Explain inductive and electromeric effect with examples.
Electromeric effect.
Which of the following hydrogens is most easily abstracted on reaction with bromine?